|
|
[1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-4-(beta-D-ribofuranosyl)aminobenzene_5''-phosphate + reduced_acceptor <=> [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-D-ribitol_5''-phosphate + acceptor
|
not assigned
|
–
|
|
MetaCyc:
RXN-10010
|
|
|
|
[1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-alpha_-D-_ribofuranosyl_triphosphate]-D-ribitol + (S)-2-hydroxyglutarate <=> 7,8-dihydromethanopterin + diphosphate
|
not assigned
|
–
|
|
MetaCyc:
RXN-10014
|
|
|
|
7,8-dihydroneopterin <=> glycolaldehyde + 2-Amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine
|
4.1.2.25
dihydroneopterin aldolase
|
–
|
|
BRENDA:
BR357
KEGG:
R03504
MetaCyc:
H2NEOPTERINALDOL-RXN
SABIO-RK:
3293
|
|
|
|
4-hydroxybenzoate + 5-phospho-alpha-D-ribose_1-diphosphate + H+ <=> 4-(beta-D-ribofuranosyl)hydroxybenzene_5''-phosphate + CO2 + diphosphate
|
2.4.2.54
beta-ribofuranosylphenol 5'-phosphate synthase
|
–
|
|
BRENDA:
BR50429
KEGG:
R11102
MetaCyc:
RXN-8124
|
|
|
|
5,6,7,8-tetrahydromethanopterin + acceptor <=> 7,8-dihydromethanopterin + reduced_acceptor
|
1.5.99.15
dihydromethanopterin reductase (acceptor)
|
–
|
|
KEGG:
R10802
MetaCyc:
RXN-15555
|
|
|
|
[1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-alpha_-D-_ribofuranosyl_5-phosphate]-D-ribitol + ATP <=> [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-alpha_-D-_ribofuranosyl_triphosphate]-D-ribitol + AMP
|
not assigned
|
–
|
|
MetaCyc:
RXN-10013
|
|
|
|
4-(beta-D-ribofuranosyl)-N-succinylaminobenzene_5''-phosphate <=> 4-(beta-D-ribofuranosyl)aminobenzene-5''-phosphate + fumarate
|
4.3.2
|
–
|
|
MetaCyc:
RXN-15742
|
|
|
|
4-(beta-D-ribofuranosyl)aminobenzene-5''-phosphate + [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl_diphosphate <=> [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-4-(beta-D-ribofuranosyl)aminobenzene_5''-phosphate + diphosphate
|
2.5.1.105
7,8-dihydropterin-6-yl-methyl-4-(beta-D-ribofuranosyl)aminobenzene 5'-phosphate synthase
|
–
|
|
MetaCyc:
RXN-15734
|
|
|
|
S-adenosyl-L-methionine + 5,10-methylenetetrahydromethanopterin + 2-Amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine + [4Fe-4S]+1_iron-sulfur_cluster + reduced_acceptor <=> 2-amino-6-[1-hydroxyethyl]-7-methyl-7,8-dihydropterin + 5''-deoxyadenosine + L-methionine + 7,8-dihydromethanopterin + [4Fe-4S]2+ + acceptor
|
2.1.1
|
–
|
|
MetaCyc:
RXN-15732
|
|
|
|
[1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-D-ribitol + 5-phospho-alpha-D-ribose_1-diphosphate <=> [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-5-[1-alpha_-D-_ribofuranosyl_5-phosphate]-D-ribitol + diphosphate
|
2.4.2
|
–
|
|
MetaCyc:
RXN-10012
|
|
|
|
2-amino-6-[1-hydroxyethyl]-7-methyl-7,8-dihydropterin + ATP <=> [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl_diphosphate + AMP + H+
|
2.7.6.3
2-amino-4-hydroxy-6-hydroxymethyldihydropteridine diphosphokinase
|
–
|
|
MetaCyc:
RXN-15733
|
|
|
|
4-(beta-D-ribofuranosyl)hydroxybenzene_5''-phosphate + L-aspartate + ATP <=> 4-(beta-D-ribofuranosyl)-N-succinylaminobenzene_5''-phosphate + ADP + phosphate + H+
|
6.3.1
|
–
|
|
MetaCyc:
RXN-15741
|
|
|
|
chorismate <=> 4-hydroxybenzoate + pyruvate
|
4.1.3.40
chorismate lyase
|
–
|
|
BRENDA:
BR48792
KEGG:
R01302
MetaCyc:
CHORPYRLY-RXN
|
|
|
|
[1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-D-ribitol_5''-phosphate + H2O <=> [1-(2-amino-7-methyl-4-oxo-7,8-dihydro-3H-pteridin-6-yl)]ethyl-(4-aminophenyl)-1-deoxy-D-ribitol + phosphate
|
3.1.3
|
–
|
|
MetaCyc:
RXN-10011
|
|